Mechanistic studies on the reaction between R2N-NONOates and aquacobalamin: evidence for direct transfer of a nitroxyl group from R2N-NONOates to cobalt(III) centers

Angew Chem Int Ed Engl. 2009;48(47):8909-13. doi: 10.1002/anie.200904360.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Alkenes / chemistry
  • Catalysis
  • Cobalt / chemistry*
  • Hydrazines / chemistry
  • Kinetics
  • Magnetic Resonance Spectroscopy
  • Nitric Oxide Donors / chemistry*
  • Nitrogen Oxides / chemistry*
  • Nitroso Compounds / chemistry
  • Spectrophotometry, Ultraviolet
  • Vitamin B 12 / analogs & derivatives*
  • Vitamin B 12 / chemistry

Substances

  • 1-hexanamine-6-(2-hydroxy-1-methyl-2-nitrosohydrazine)-N-methyl
  • Alkenes
  • Hydrazines
  • Nitric Oxide Donors
  • Nitrogen Oxides
  • Nitroso Compounds
  • dipropylenetriamine-NONOate
  • aquacobalamin
  • 2,2'-(hydroxynitrosohydrazono)bis-ethanamine
  • Cobalt
  • 1,1-diethyl-2-hydroxy-2-nitrosohydrazine
  • nitroxyl
  • Vitamin B 12