Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-)

Natalya V Izarova; Michael H Dickman; Rosa Ngo Biboum; Bineta Keita; Louis Nadjo; Vasanth Ramachandran; Naresh S Dalal; Ulrich Kortz

doi:10.1021/ic900953a

Heteropoly-13-palladates(II) [Pd(II)(13)(As(V)Ph)(8)O(32)](6-) and [Pd(II)(13)Se(IV)(8)O(32)](6-)

Inorg Chem. 2009 Aug 17;48(16):7504-6. doi: 10.1021/ic900953a.

Authors

Natalya V Izarova¹, Michael H Dickman, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Vasanth Ramachandran, Naresh S Dalal, Ulrich Kortz

Affiliation

¹ Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany.

PMID: 19722682
DOI: 10.1021/ic900953a

Abstract

Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.