Abstract
The ring-opening of N-tosylaziridines with silylated nucleophiles catalyzed by tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP) afforded the corresponding beta-functionalized sulfonamides in excellent yield under mild reaction conditions.
MeSH terms
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Aziridines / chemistry*
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Catalysis
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Cyanides / chemistry
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Organosilicon Compounds / chemistry*
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Phosphines / chemistry*
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Trimethylsilyl Compounds / chemistry
Substances
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Aziridines
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Cyanides
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Organosilicon Compounds
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Phosphines
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Trimethylsilyl Compounds
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tris(2,4,6-trimethoxyphenyl)phosphine
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aziridine
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trimethylsilyl cyanide