Theoretical study of CH4-CH4, CHF3-CH4, CH4-H2O, and CHF3-H2O dimers

J Phys Chem A. 2009 Dec 31;113(52):14818-23. doi: 10.1021/jp904962b.

Abstract

We have studied systems with typical hydrogen bonding and others with interaction involving hydrogen. CH(4)-CH(4), CH(4)-H(2)O, CHF(3)-CH(4), and CHF(3)-H(2)O dimers were studied using MPWB1K, PBE1PBE, MP2, and QCISD levels of theory with a large number of basis functions. The Pople 6-31+G(2d), 6-311++G(2d,2p), and 6-311++G(3df,3pd) as well as Dunning augmented aug-cc-pVDZ and aug-cc-pVTZ basis sets were used. The dimer geometries were fully optimized. An optimal basis set was determined for these systems to achieve a suitable compromise between accuracy and computational feasibility. A proper strategy was found for the electronic property calculations of dimers studied: the use of aug-cc-pVDZ as the optimal basis set at MP2 level. Dipole moments, polarizabilities, BSSE effects, and DeltaZPE were also analyzed for these dimers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chlorofluorocarbons, Methane / chemistry*
  • Dimerization*
  • Methane / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Quantum Theory*
  • Thermodynamics
  • Water / chemistry*

Substances

  • Chlorofluorocarbons, Methane
  • Water
  • Methane
  • fluoroform