Carbon-silicon core-shell nanowires as high capacity electrode for lithium ion batteries

Nano Lett. 2009 Sep;9(9):3370-4. doi: 10.1021/nl901670t.

Abstract

We introduce a novel design of carbon-silicon core-shell nanowires for high power and long life lithium battery electrodes. Amorphous silicon was coated onto carbon nanofibers to form a core-shell structure and the resulted core-shell nanowires showed great performance as anode material. Since carbon has a much smaller capacity compared to silicon, the carbon core experiences less structural stress or damage during lithium cycling and can function as a mechanical support and an efficient electron conducting pathway. These nanowires have a high charge storage capacity of approximately 2000 mAh/g and good cycling life. They also have a high Coulmbic efficiency of 90% for the first cycle and 98-99.6% for the following cycles. A full cell composed of LiCoO(2) cathode and carbon-silicon core-shell nanowire anode is also demonstrated. Significantly, using these core-shell nanowires we have obtained high mass loading and an area capacity of approximately 4 mAh/cm(2), which is comparable to commercial battery values.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon / chemistry*
  • Electric Power Supplies*
  • Electrodes
  • Ions / chemistry
  • Lithium / chemistry*
  • Materials Testing
  • Nanotechnology
  • Nanowires / chemistry*
  • Particle Size
  • Silicon / chemistry*
  • Surface Properties

Substances

  • Ions
  • Carbon
  • Lithium
  • Silicon