Abstract
Selective mono or double carbonylations could be achieved by using CO(2)-expanded liquids in [2 + 2 + 1] carbonylative reactions of alkenes or acetylenes with allyl bromides catalyzed by Ni(i).
MeSH terms
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Acetone / chemistry*
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Alkynes / chemistry
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Allyl Compounds / chemistry
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Carbon Dioxide / chemistry*
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Catalysis
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Cyclization
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Molecular Structure
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Nickel / chemistry*
Substances
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Alkynes
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Allyl Compounds
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Acetone
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Carbon Dioxide
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Nickel