The effect of surface roughness on the plasmonic response of individual sub-micron gold spheres

Phys Chem Chem Phys. 2009 Jul 28;11(28):5909-14. doi: 10.1039/b905200n. Epub 2009 May 15.

Abstract

Nanoscale surface corrugation strongly determines the plasmonic response of gold nanoparticles with dimensions of several tens of nanometres. Scattering spectra of individual spheres with a rough surface were found to red-shift and broaden. The plasmon modes exhibited quadrupole damping, in contrast to particles with smooth surfaces. Additionally, rougher spheres display a higher SERS activity, which demonstrates the crucial role of nanoscale surface texturing on the plasmonic response of gold particles.

Publication types

  • Research Support, Non-U.S. Gov't