Prototypes of molecular motors based on star-shaped organometallic ruthenium complexes

Chem Soc Rev. 2009 Jun;38(6):1551-61. doi: 10.1039/b804684k. Epub 2009 Feb 23.

Abstract

This tutorial review presents our strategy to control the rotation in a molecular rotary motor, and the family of star-shaped ruthenium complexes designed to perform such a task. The molecules have a piano-stool structure with a "stator" meant to be grafted on a surface, and a "rotor" bearing redox-active groups, so that addressing the molecule with nano-electrodes would trigger rotation.