1 Institute of Chemical and Engineering Sciences, Agency for Science, Technology and Research (A*STAR), 1 Pesek Rd, Jurong Island, Singapore 627833, Singapore.
A novel supramolecular star polymer is reported, which can be prepared either from atom-transfer radical polymerization (ATRP) of a self-assembled initiator or from self-assembly of a guanosine-capped linear polymer.