Abstract
This communication describes a highly efficient aziridinyl polyolefin cyclization catalyzed by InBr(3) to synthesize chiral terpenoid bearing a 3-amino group in the A ring; both good yields and excellent asymmetric induction were achieved.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Aziridines / chemistry*
-
Biomimetics*
-
Catalysis
-
Cyclization
-
Indium / chemistry*
-
Polyenes / chemistry*
-
Stereoisomerism
-
Substrate Specificity
-
Terpenes / chemical synthesis
-
Terpenes / chemistry
Substances
-
Aziridines
-
Polyenes
-
Terpenes
-
indium bromide
-
Indium
-
aziridine