Relaxations as key to the magnetocapacitive effects in the perovskite manganites

Phys Rev Lett. 2009 May 22;102(20):207208. doi: 10.1103/PhysRevLett.102.207208. Epub 2009 May 22.

Abstract

We present a detailed dielectric study of the relaxation effects that occur in several perovskite rare-earth manganites, including the multiferroics TbMnO(3) and DyMnO(3). We demonstrate that the strong magnetocapacitive effects, observed for electrical fields E parallel c, are nearly completely governed by magnetic-state induced changes of the relaxation parameters. The multiferroic materials, which undergo a transition into a spiral magnetic state, show qualitatively different relaxation behavior than those compounds transferring into an A-type antiferromagnetic state. We ascribe the relaxations in both cases to the off-center motion of the manganese ions, which in the multiferroic systems also leads to the ferroelectric ordering.