Crystal structure of highly concentrated, ionic microgel suspensions studied by neutron scattering

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 May;79(5 Pt 1):051403. doi: 10.1103/PhysRevE.79.051403. Epub 2009 May 12.

Abstract

We present a neutron-scattering investigation of the crystal structure formed by pH -sensitive poly(2-vinylpyridine) microgel particles with 5 wt % of cross-linker. We focus on highly swollen particles and explore concentrations ranging from below close packing to well above close packing, where the particles are forced to shrink and/or interpenetrate. The crystal structure is found to be random hexagonal close packed, similar to the structure typically found in hard-sphere systems.

Publication types

  • Research Support, Non-U.S. Gov't