Beyond Cahn-Hilliard-Cook ordering theory: early time behavior of spatial-symmetry-breaking phase transition kinetics

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Apr;79(4 Pt 1):042104. doi: 10.1103/PhysRevE.79.042104. Epub 2009 Apr 28.

Abstract

We extend the early time ordering theory of Cahn, Hilliard, and Cook (CHC) so that our generalized theory applies to solid-to-solid transitions. Our theory involves spatial-symmetry breaking (the initial phase contains a symmetry not present in the final phase). The predictions of our generalization differ from those of the CHC theory in two important ways: exponential growth does not begin immediately following the quench and the objects that grow exponentially are not necessarily Fourier modes. Our theory is consistent with simulation results for the long-range antiferromagnetic Ising model.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.