Mechanism for stripe pattern formation on hydrophilic surfaces by using convective self-assembly

Langmuir. 2009 Jul 7;25(13):7287-95. doi: 10.1021/la900315h.

Abstract

We have studied the formation of stripe patterned films of ordered particle arrays on completely solvophilic substrates by using a self-organization technique. In this method, a substrate immersed in a suspension is withdrawn vertically at a controlled temperature. We have also systematically examined the effects of several experimental parameters. Well-defined stripes spontaneously form at the air-solvent-substrate contact line because of a very dilute suspension in a quasi-static process. The stripe width depends on particle concentration, withdrawal rate, and surface tension, while the stripe spacing depends on the thickness of stripes, surface tension, and type of substrate. A stripe width and the adjacent spacing show a clear correlation, strongly indicating the synchronized formation of a stripe and the next spacing. The evaporation rate does not affect stripe width and spacing but determines the growth rate of stripe patterned films. Based on these results, we propose a new mechanism for stripe formation, which is neither a stick-slip motion of the contact line nor dewetting but a negative feedback of particle concentration caused by a concavely curved shape of the meniscus, demonstrating not only its qualitative but also its quantitative validity.

MeSH terms

  • Microscopy, Electron, Scanning
  • Silicon Dioxide / chemistry*
  • Surface Properties
  • Water / chemistry*

Substances

  • Water
  • Silicon Dioxide