On the influence of nanotube properties, processing conditions and shear forces on the electrical conductivity of carbon nanotube epoxy composites

Nanotechnology. 2009 Apr 15;20(15):155703. doi: 10.1088/0957-4484/20/15/155703. Epub 2009 Mar 25.

Abstract

We analyse statistical and kinetic percolation thresholds and maximum electrical conductivities of carbon nanotube epoxy composites as a function of shear forces, processing conditions, nanotube type and dimensions. Entangled and non-entangled nanotubes of different lengths (15-100 microm) and thicknesses (12-80 nm) have been obtained with three different synthesis methods based on catalytic or plasma enhanced chemical vapour deposition. The dispersions were processed either solely with a dissolver disk or additionally with a three roll calender. Care was taken to prevent unintentional shearing (e.g. through convection) in all samples that were not subject to deliberate shearing. It was found that shear forces have a similar influence on kinetic percolation thresholds and composite conductivities independent of nanotube types and dimensions.

Publication types

  • Research Support, Non-U.S. Gov't