Pair potential of charged colloidal stars

Phys Rev Lett. 2009 Mar 13;102(10):108302. doi: 10.1103/PhysRevLett.102.108302. Epub 2009 Mar 10.

Abstract

We report on the construction of colloidal stars: 1 microm polystyrene beads grafted with a dense brush of 1 microm long and 10 nm wide charged semiflexible filamentous viruses. The pair interaction potentials of colloidal stars are measured using an experimental implementation of umbrella sampling, a technique originally developed in computer simulations in order to probe rare events. The influence of ionic strength and grafting density on the interaction is measured. Good agreements are found between the measured interactions and theoretical predictions based upon the osmotic pressure of counterions.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Algorithms
  • Bacteriophage M13 / chemistry*
  • Capsid Proteins / chemistry*
  • Colloids / chemical synthesis
  • Colloids / chemistry*
  • Computer Simulation
  • Fluorescence
  • Gold / chemistry
  • Microscopy, Electron, Transmission
  • Osmolar Concentration
  • Polystyrenes / chemistry*

Substances

  • Capsid Proteins
  • Colloids
  • Polystyrenes
  • Gold