New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers

Lei Liu; Stanislav Ferdov; Cristina Coelho; Ying Kong; Luís Mafra; Jin P Li; Jin X Dong; Uwe Kolitsch; Rute A Sá Ferreira; Ekkehart Tillmanns; João Rocha; Zhi Lin

doi:10.1021/ic900107p

New crystalline layered zinc phosphate with 10-membered-ring channels perpendicular to layers

Inorg Chem. 2009 Jun 1;48(11):4598-600. doi: 10.1021/ic900107p.

Authors

Lei Liu¹, Stanislav Ferdov, Cristina Coelho, Ying Kong, Luís Mafra, Jin P Li, Jin X Dong, Uwe Kolitsch, Rute A Sá Ferreira, Ekkehart Tillmanns, João Rocha, Zhi Lin

Affiliation

¹ Research Institute of Special Chemicals, Taiyuan University of Technology, 030024 Taiyuan, People's Republic of China.

PMID: 19378938
DOI: 10.1021/ic900107p

Abstract

A novel layered zinc phosphate, [N(2)C(6)H(12)](2)[Zn(7)H(3)(HPO(4-x))(5)(PO(4))(3)]H(2)O, with unique 10-membered-ring ellipsoidal channels running perpendicularly to ladder-shaped tetrahedral layers, has been synthesized ionothermally via in situ generation of 1,4-diazabicyclo[2.2.2]octane.