Remediation of PAH spiked soils: concentrated H2O2 treatment/continuous hot water extraction-oxidation

J Hazard Mater. 2009 Sep 15;168(2-3):1359-65. doi: 10.1016/j.jhazmat.2009.03.017. Epub 2009 Mar 18.

Abstract

Artificially contaminated soil with four different polynuclear aromatic hydrocarbons (acenaphthene, phenathrene, anthracene and fluoranthene) has been separately treated by two different processes: (A) concentrated hydrogen peroxide at mild conditions of temperature (343-393 K) and pressure (0.5 MPa) and (B) hot water extraction at relatively high temperature (523-657 K) and pressure (10 MPa). Both methods achieve acceptable PAH removal percentages from soil. Acenaphthene (the most soluble PAH) is completely removed with treatment A regardless of the operating conditions used. Under optimum conditions, the rest of PAHs are also eliminated to a high extent with both technologies. Temperature and hydrogen peroxide amount seem to play a major role in process A. Similarly, temperature and water flowrate are the most influencing parameters in process B. In the latter case, a post-stage for the extracting water cleaning is required.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrogen Peroxide / chemistry*
  • Oxidation-Reduction
  • Polycyclic Compounds / isolation & purification*
  • Soil Pollutants / isolation & purification*
  • Water / chemistry

Substances

  • Polycyclic Compounds
  • Soil Pollutants
  • Water
  • Hydrogen Peroxide