Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex

Angew Chem Int Ed Engl. 2009;48(17):3161-4. doi: 10.1002/anie.200900435.

Abstract

Y not? A unique, three-coordinate Y-shaped bis(silyl)platinum(II) complex was isolated and characterized (see structure; C light gray, N blue, Si pink, Pt dark gray). DFT studies on a model system shed light on the nature of this unusual coordination mode for platinum(II).