High-valent manganese(v)-oxo porphyrin complexes in hydride transfer reactions

Chem Commun (Camb). 2009 Feb 14:(6):704-6. doi: 10.1039/b814928c. Epub 2008 Dec 19.

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to trans-dioxomanganese(v) porphyrin complexes proceeds via proton-coupled electron transfer, followed by rapid electron transfer.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrogen / chemistry*
  • Manganese / chemistry*
  • Metalloporphyrins / chemistry*
  • NAD / chemistry
  • Spectrophotometry, Ultraviolet

Substances

  • Metalloporphyrins
  • NAD
  • Manganese
  • Hydrogen