A tris(alkyl)yttrium compound containing six beta-agostic Si-H interactions

Chem Commun (Camb). 2009 Feb 14:(6):656-8. doi: 10.1039/b818630h. Epub 2008 Dec 12.

Abstract

The new homoleptic rare earth compound [Y(C(SiHMe(2))(3))(3)] () is prepared in 82% yield by salt metathesis of YCl(3) and 3 equivalents of [KC(SiHMe(2))(3)] (); two beta-agostic Y(H-Si) interactions are observed for each C(SiHMe(2))(3) ligand in , giving six agostic interactions per yttrium(iii) center.