An approaching study to the electrochemical degradation of perchloroethylene (PCE) in water has been carried out using controlled current density degradation electrolyses. The different electrochemical strategies to degrade perchloroethylene in aqueous media (i.e. cathodic, anodic and dual treatments) have been checked using divided and undivided configurations. The influence of the initial concentration, pH and current density on the general behavior of the system has been studied, and special attention was paid to the nature of the byproducts formed and to the analysis of the closed mass balance at the end of the reaction. Results from several analytical techniques have been compared. Undivided configuration provides the best results in these experimental conditions, with degradation percentages higher than 50% and with only 6% of the initial perchloroethylene concentration remaining in the system.