Silver-catalysed Doyle-Kirmse reaction of allyl and propargyl sulfides

Org Biomol Chem. 2009 Apr 7;7(7):1276-9. doi: 10.1039/b822584b. Epub 2009 Feb 13.

Abstract

The silver-catalysed Doyle-Kirmse reaction of propargyl and allyl sulfides with diazo compounds is disclosed. The carbon-carbon bond forming process proceeds with a range of substituents and functionality under mild conditions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkynes / chemistry*
  • Allyl Compounds / chemistry*
  • Azo Compounds / chemistry
  • Catalysis
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Silver / chemistry*
  • Stereoisomerism
  • Sulfides / chemical synthesis*
  • Sulfides / chemistry*

Substances

  • Alkynes
  • Allyl Compounds
  • Azo Compounds
  • Organometallic Compounds
  • Sulfides
  • Silver