Diastereoselective synthesis of chiral diporphyrins via intramolecular meso-meso oxidative coupling

J Org Chem. 2009 Apr 17;74(8):3164-7. doi: 10.1021/jo9001118.

Abstract

Diastereoselective syntheses of meso-meso linked diporphyrins were achieved via intramolecular chiral induction. The structures and conformations were analyzed by CD, UV, NMR, and computational calculations.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Magnetic Resonance Spectroscopy
  • Metalloporphyrins / chemical synthesis*
  • Metalloporphyrins / chemistry
  • Models, Molecular
  • Molecular Structure
  • Oxidation-Reduction
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry
  • Spectrophotometry, Ultraviolet
  • Stereoisomerism
  • Zinc / chemistry

Substances

  • Metalloporphyrins
  • Porphyrins
  • Zinc