Experimental observation of the crystallization of hard-sphere colloidal particles by sedimentation onto flat and patterned surfaces

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Jan;79(1 Pt 1):011403. doi: 10.1103/PhysRevE.79.011403. Epub 2009 Jan 21.

Abstract

We present a confocal microscopy study of 1.55 microm monodisperse silica hard spheres as they sediment and crystallize at the bottom wall of a container. If the particles sediment onto a feature less flat wall, the two bottom layers crystallize simultaneously and layerwise growth follows. If the wall is replaced by a hexagonal template, only layerwise growth occurs. Our results complement earlier numerical simulations and experiments on other colloidal systems.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.