Is cyanide really a strong-field ligand?

Angew Chem Int Ed Engl. 2009;48(15):2638-40. doi: 10.1002/anie.200805446.

Abstract

Iron man or weakling? Ligand-field strengths are conveniently expressed by the empirical spectrochemical series. Although cyanide has been deeply entrenched as a strong-field ligand, a couple of recent examples cast doubt toward the position of this ligand, namely the high-spin (S = 2) states of [Cr(II)(CN)(5)](3-) and [Fe(II)(tpp)(CN)](-). tpp = meso-tetraphenylporphinate.

Publication types

  • Comment

MeSH terms

  • Chromium / chemistry
  • Cyanides / chemistry*
  • Iron / chemistry
  • Ligands
  • Organometallic Compounds / chemistry

Substances

  • Cyanides
  • Ligands
  • Organometallic Compounds
  • Chromium
  • Iron