Three-dimensional shapes and structures of lamellar-twinned fcc nanoparticles using ADF STEM

J Electron Microsc (Tokyo). 2009 Jun;58(3):167-74. doi: 10.1093/jmicro/dfp003. Epub 2009 Feb 11.

Abstract

Small particles with face-centred cubic structures can have non-single-crystallographic shapes. Here, an approach based on annular dark-field scanning transmission electron microscopy (STEM) is used to obtain information about the crystal sub-units that make up supported and unsupported twinned Pt, Pt alloy and Au nanoparticles. The three-dimensional shapes of two types of lamellar-twinned particles (LTPs) of Pt are obtained using high-angle annular dark-field STEM. Possible growth mechanisms of the LTPs and origins for the contrast features in the recorded images are discussed.

Publication types

  • Research Support, Non-U.S. Gov't