Pseudo-capsule assemblies characterized by 19F NMR techniques

J Am Chem Soc. 2009 Feb 25;131(7):2440-1. doi: 10.1021/ja809224p.

Abstract

The formation of capsule-like dynamic assemblies which do not rely on attractions between host subunits was achieved via specific interactions with fluorinated guests. Characterization of these three component assemblies was accomplished by applications of (19)F NMR spectroscopy.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adamantane / chemistry
  • Alkynes / chemistry
  • Calixarenes / chemistry
  • Ethers, Cyclic / chemistry
  • Fluorine / chemistry
  • Hydrocarbons, Fluorinated / chemistry*
  • Iodobenzenes / chemistry
  • Kinetics
  • Magnetic Resonance Spectroscopy / methods*
  • Models, Molecular
  • Molecular Conformation
  • Phenylalanine / analogs & derivatives
  • Phenylalanine / chemistry
  • Resorcinols / chemistry

Substances

  • Alkynes
  • Ethers, Cyclic
  • Hydrocarbons, Fluorinated
  • Iodobenzenes
  • Resorcinols
  • cavitand
  • resorcinarene
  • Calixarenes
  • Fluorine
  • Phenylalanine
  • Adamantane