Abstract
Enlarged scope by fluorinated mediators: Oxyl radicals are easily formed on boron-doped diamond (BDD) electrodes and can be exploited for the ortho-selective coupling to the corresponding biphenols (see scheme). At partial conversion, a clean transformation is achieved that can be applied to electron-rich as well as fluorinated phenols.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemistry*
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Boron / chemistry*
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Diamond / chemistry*
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Electrochemistry / instrumentation
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Electrochemistry / methods
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Electrodes
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Hydrocarbons, Fluorinated / chemistry
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Models, Molecular
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Oxidation-Reduction
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Phenols / chemical synthesis*
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Phenols / chemistry
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Propanols / chemistry
Substances
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Alcohols
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Hydrocarbons, Fluorinated
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Phenols
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Propanols
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hexafluoroisopropanol
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Diamond
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Boron