Abstract
Lanthanide triisopropoxides catalyze a rapid, tandem MPV reduction/Brook rearrangement/aldol sequence between silyl glyoxylates and aldehydes that achieves catalytic turnover through alkoxide transfer from a strain-release Lewis acidic silacycle.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Aldehydes / chemistry*
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Catalysis
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Glyoxylates / chemistry*
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Lanthanoid Series Elements / chemistry
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Molecular Structure
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Oxidation-Reduction
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Silanes / chemistry*
Substances
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Aldehydes
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Glyoxylates
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Lanthanoid Series Elements
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Silanes
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3-hydroxybutanal