Mathematical form factor studies on the effect of water on airborne particles morphology using a bi-dimensional TEM image processing

J Environ Monit. 2009 Jan;11(1):181-6. doi: 10.1039/b806940a. Epub 2008 Nov 7.

Abstract

Mathematical morphology is a tool for extracting image components that are useful for representation and description. The technique consists of a set-theoretic method of image analysis providing a quantitative description of geometrical structures. A simple application of mathematical morphology to a bi-dimensional processing of TEM images of airborne particles allows us to distinguish between particles grown and/or transported in atmosphere under dry conditions or in rainy days by a simple comparison of the corresponding image form factors. The form factors range in the 0.385-0.031 interval in the case of particles sampled in rainy days, and in the 0.103-0.006 interval in the case of non-rainy conditions. The same classification criterion was applied to filters collected under dry conditions and plunged in water. The results demonstrate that a morphological change may be artificially induced to the particle structure. The artificially wet particles, indeed, display an apparent contraction of their structures evidenced by a two-fold increase of the average values of their form factors. The last experiment roughly simulates the impact of particles on membranes of the respiratory tract.

MeSH terms

  • Mathematical Computing
  • Microscopy, Electron, Transmission
  • Models, Theoretical
  • Particle Size
  • Particulate Matter / analysis*
  • Soot / analysis*
  • Soot / chemistry
  • Surface Properties
  • Water*

Substances

  • Particulate Matter
  • Soot
  • Water