Spectroscopic properties and energy transfer of Tm(3+)/Ho(3+)-codoped TeO(2)-WO(3)-ZnO glasses for 1.47mum amplifier

Spectrochim Acta A Mol Biomol Spectrosc. 2009 May;72(4):734-7. doi: 10.1016/j.saa.2008.11.014. Epub 2008 Nov 21.

Abstract

We report on spectroscopic properties and energy transfer of Tm(3+)/Ho(3+)-codoped tungsten tellurite glasses for 1.47microm amplifier. Fluorescence spectra and the analysis of energy transfer indicate that Ho(3+) is an excellent codopant for 1.47microm emission. Comparing with other tellurite glasses, the radiative lifetime of the (3)H(4) level of Tm(3+) in tungsten tellurite glass is slightly lower, but the spontaneous emission probability, stimulated emission cross-section and the figure of merit for bandwidth are obviously larger. Although the pump efficiency of tungsten tellurite amplifier is approximately 50% less than that of fluoride glass, the figure of merit for bandwidth is approximately three times larger in tungsten tellurite glass than in fluoride glass. The results indicate that Tm(3+)/Ho(3+)-codoped tungsten tellurite glass is attractive for broadband amplifier.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Glass / chemistry*
  • Holmium / chemistry*
  • Oxides / chemistry*
  • Spectrum Analysis
  • Tellurium / chemistry*
  • Thulium / chemistry*
  • Tungsten / chemistry*
  • Zinc Oxide / chemistry*

Substances

  • Oxides
  • tellurium dioxide
  • Thulium
  • tungsten oxide
  • Tellurium
  • Zinc Oxide
  • Tungsten
  • Holmium