Real time and in situ determination of lead in road sediments using a man-portable laser-induced breakdown spectroscopy analyzer

Anal Chim Acta. 2009 Feb 2;633(1):38-42. doi: 10.1016/j.aca.2008.11.045. Epub 2008 Nov 27.

Abstract

In situ, real time levels of lead in road sediments have been measured using a man-portable laser-induced breakdown spectroscopy analyzer. The instrument consists of a backpack and a probe housing a Q-switched Nd:YAG laser head delivering 50 mJ per pulse at 1064 nm. Plasma emission was collected and transmitted via fiber optic to a compact cross Czerny-Turner spectrometer equipped with a linear CCD array allocated in the backpack together with a personal computer. The limit of detection (LOD) for lead and the precision measured in the laboratory were 190 microg g(-1) (calculated by the 3 sigma method) and 9% R.S.D. (relative standard deviation), respectively. During the field campaign, averaged Pb concentration in the sediments were ranging from 480 microg g(-1) to 660 microg g(-1) depending on the inspected area, i.e. the entrance, the central part and the exit of the tunnel. These results were compared with those obtained with flame-atomic absorption spectrometry (flame-AAS). The relative error, expressed as [100(LIBS result-flame AAS result)/(LIBS result)], was approximately 14%.

Publication types

  • Comparative Study
  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Environmental Monitoring / instrumentation
  • Environmental Monitoring / methods
  • Lasers
  • Lead / analysis*
  • Sensitivity and Specificity
  • Soil / analysis
  • Spectrum Analysis / instrumentation
  • Spectrum Analysis / methods*
  • Time Factors

Substances

  • Soil
  • Lead