Gold-catalyzed hydroalkoxylation of alkoxyallenes

J Org Chem. 2009 Feb 6;74(3):1426-7. doi: 10.1021/jo802513a.

Abstract

We report synthesis of allylic acetals via gold-catalyzed hydroalkoxylation of alkoxyallenes with alcohols containing primary and secondary alcohols in good to excellent yields under mild condition.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetals / chemical synthesis*
  • Alcohols / chemistry*
  • Alkadienes / chemistry*
  • Alkenes / chemical synthesis
  • Benzene Derivatives / chemical synthesis
  • Benzene Derivatives / chemistry
  • Catalysis
  • Ethers / chemical synthesis*
  • Ethers / chemistry
  • Gold / chemistry

Substances

  • Acetals
  • Alcohols
  • Alkadienes
  • Alkenes
  • Benzene Derivatives
  • Ethers
  • propadiene
  • Gold