Abstract
N-substituted glycine peptoid oligomers bearing hydroxyquinoline ligands form complexes with Cu(ii) and Co(ii) in which the chiral helical secondary structure of the foldamers is enhanced upon metal binding and establishes a stereogenic environment for metal coordination.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Chromatography, High Pressure Liquid
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Cobalt / chemistry*
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Copper / chemistry*
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Hydroxyquinolines / chemistry*
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Models, Molecular
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Oligopeptides / chemical synthesis*
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Oligopeptides / chemistry
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Protein Conformation
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Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
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Spectrophotometry, Ultraviolet
Substances
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Hydroxyquinolines
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Oligopeptides
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Cobalt
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Copper