First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold

Derya Cetiner; Béatrice Jacques; Elina Payet; Murielle Chavarot-Kerlidou; Françoise Rose-Munch; Eric Rose; Jean-Philippe Tranchier; Patrick Herson

doi:10.1039/b817192k

First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold

Dalton Trans. 2009 Jan 7:(1):27-9. doi: 10.1039/b817192k. Epub 2008 Nov 17.

Authors

Derya Cetiner¹, Béatrice Jacques, Elina Payet, Murielle Chavarot-Kerlidou, Françoise Rose-Munch, Eric Rose, Jean-Philippe Tranchier, Patrick Herson

Affiliation

¹ UPMC Univ Paris 06, UMR CNRS 7611, Laboratoire de Chimie Organique, Institut de Chimie Moléculaire (FR 2769), Case 181, 4 place Jussieu, F-75252, Paris Cedex 05, France.

PMID: 19081966
DOI: 10.1039/b817192k

Abstract

The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.