Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units

Shinya Takaishi; Miyuki Hosoda; Takashi Kajiwara; Hitoshi Miyasaka; Masahiro Yamashita; Yasuyuki Nakanishi; Yasutaka Kitagawa; Kizashi Yamaguchi; Atsushi Kobayashi; Hiroshi Kitagawa

doi:10.1021/ic802117q

Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units

Inorg Chem. 2009 Oct 5;48(19):9048-50. doi: 10.1021/ic802117q.

Authors

Shinya Takaishi¹, Miyuki Hosoda, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Yasuyuki Nakanishi, Yasutaka Kitagawa, Kizashi Yamaguchi, Atsushi Kobayashi, Hiroshi Kitagawa

Affiliation

¹ Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan. takaishi@agnus.chem.tohoku.ac.jp

PMID: 19067544
DOI: 10.1021/ic802117q

Abstract

We synthesized a new porous coordination polymer Cu[Cu(pdt)2], which shows relatively high electrical conductivity (6 x 10(-4) S cm(-1) at 300 K) by the introduction of electron donors and acceptors as building units. This compound is applicable as a porous electrode with high power density. In addition, this compound forms a triangular spin lattice and shows spin frustration.