Solution phase, solid state, and theoretical investigations on the MacMillan imidazolidinone

John B Brazier; Gareth Evans; Timothy J K Gibbs; Simon J Coles; Michael B Hursthouse; James A Platts; Nicholas C O Tomkinson

doi:10.1021/ol802512y

Solution phase, solid state, and theoretical investigations on the MacMillan imidazolidinone

Org Lett. 2009 Jan 1;11(1):133-6. doi: 10.1021/ol802512y.

Authors

John B Brazier¹, Gareth Evans, Timothy J K Gibbs, Simon J Coles, Michael B Hursthouse, James A Platts, Nicholas C O Tomkinson

Affiliation

¹ School of Chemistry, Main Building, Cardiff University, Park Place, Cardiff, CF10 3AT, United Kingdom.

PMID: 19061422
DOI: 10.1021/ol802512y

Abstract

A combination of solution phase NMR, X-ray crystallographic studies, and DFT calculations provide a consistent structural conformation for iminium ions derived from the MacMillan imidazolidinone.

MeSH terms

Catalysis
Crystallography, X-Ray
Cyclization
Imidazolidines / chemistry*
Magnetic Resonance Spectroscopy
Models, Chemical*
Models, Molecular
Molecular Structure
Solutions

Substances

Imidazolidines
Solutions