Abstract
The first enantiopure 4,4'-bipyridyls, , , and have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline and C-C coupling; ligands and are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn(2)(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Crystallography, X-Ray
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Dioxygenases / metabolism*
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Fumarates / chemistry*
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Hydroxylation
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Ligands
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Pseudomonas putida / enzymology
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Pyridines / chemical synthesis*
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Pyridines / chemistry
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Pyridines / metabolism*
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Sphingomonas / enzymology
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Stereoisomerism
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Zinc / chemistry*
Substances
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Fumarates
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Ligands
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Organometallic Compounds
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Pyridines
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Dioxygenases
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Zinc
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4,4'-bipyridyl