Abstract
This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium-cadmium base; the reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.
MeSH terms
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Benzene Derivatives / chemistry*
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Cadmium / chemistry*
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Heterocyclic Compounds / chemistry*
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Hydrocarbons, Halogenated / chemical synthesis*
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Hydrocarbons, Halogenated / chemistry
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Lithium / chemistry*
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Models, Chemical
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Molecular Structure
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Organometallic Compounds / chemistry*
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Protons
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Stereoisomerism
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Temperature
Substances
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Benzene Derivatives
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Heterocyclic Compounds
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Hydrocarbons, Halogenated
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Organometallic Compounds
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Protons
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Cadmium
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Lithium