Design, synthesis and evaluation of diazadibenzocrown ethers as Pb(2+) extractants and carriers in plasticized cellulose triacetate membranes

J C Aguilar; E R Miguel; J Gyves; R A Bartsch; M Kim

doi:10.1016/s0039-9140(01)00387-3

Design, synthesis and evaluation of diazadibenzocrown ethers as Pb(2+) extractants and carriers in plasticized cellulose triacetate membranes

Talanta. 2001 Jul 6;54(6):1195-204. doi: 10.1016/s0039-9140(01)00387-3.

Authors

J C Aguilar¹, E R Miguel, J Gyves, R A Bartsch, M Kim

Affiliation

¹ Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad Universitaria, Mexico, D.F. 04510, Mexico.

PMID: 18968340
DOI: 10.1016/s0039-9140(01)00387-3

Abstract

The ligands 4,7-diaza-2,3,8,9-dibenzo-15-crown-5 (L1), 4,10-diaza-2,3,11,12-dibenzo-18-crown-6 (L2), 4,10-diaza-2,3,11,12-di(4'-tert-butylbenzo)-18-crown-6 (L3) and N,N-di(methylenecarboxyethoxy) 4,10-diaza-2,3,11,12-dibenzo-18-crown-6 (L4) have been prepared. Partition coefficients and acid dissociation constants for these four diazadibenzocrown ether compounds were determined in water-chloroform. Their effectiveness was assessed in solvent extraction of Pb(2+) from aqueous solutions into toluene. Ligands L3 and L4 provide high selectivity for Pb(2+) over Cd(2+) and Zn(2+) in transport across plasticized cellulose triacetate membranes.