Evaluation of adsorption potential of adsorbents: a case of uptake of cationic dyes

J Environ Biol. 2008 Jan;29(1):31-6.

Abstract

Adsorption potential of a commercial activated carbon (FS300) has been evaluated for the uptake of cationic dyes namely methylene blue (MB) and rhodamine B (RB). Though, there are numerous studies in literature which report the sorption of MB (more than 40 studies) and RB (more than 10), however none of these use a common parameter to report the capacity of the sorbent. A protocol, based on the equilibrium dye concentration has been proposed to measure the sorption potential of a sorbent. The Langmuir model can very well describe the experimental equilibrium data for both dyes (coefficient of correlation > 0.999). MB (Qm = 312.5 mg g(-1)) is more adsorbable than the RB (Qm = 144.9 mg g(-1)). Molecular weight and chemical structure of dye molecules seem to affect the dye uptake. The effect of pH on dye uptake has also been evaluated by varyingpH from 3 to 11. Uptake of MB increases with pH, wherein RB removal decreases with pH. Dyes could not be desorbed either by distilled water (0.06 and 0.11% for MB and RB respectively), or by 0.1 NHCl (0.136 and 3.0% for MB and RB respectively) indicating, chemical adsorption type of adsorbent-adsorbate interactions.

Publication types

  • Evaluation Study

MeSH terms

  • Adsorption
  • Carbon / chemistry
  • Cations / chemistry
  • Cations / isolation & purification
  • Coloring Agents / chemistry
  • Coloring Agents / isolation & purification*
  • Hydrogen-Ion Concentration
  • Methylene Blue / chemistry
  • Methylene Blue / isolation & purification
  • Models, Chemical
  • Rhodamines / chemistry
  • Rhodamines / isolation & purification
  • Waste Disposal, Fluid / methods*
  • Water Pollutants, Chemical / chemistry
  • Water Pollutants, Chemical / isolation & purification*
  • Water Purification / methods*

Substances

  • Cations
  • Coloring Agents
  • Rhodamines
  • Water Pollutants, Chemical
  • Carbon
  • rhodamine B
  • Methylene Blue