X-ray absorption measured in the resonant Auger scattering mode

Phys Rev Lett. 2008 Aug 15;101(7):073001. doi: 10.1103/PhysRevLett.101.073001. Epub 2008 Aug 11.

Abstract

We report both experimental and theoretical studies on x-ray absorption measured in the resonant Auger scattering mode of gas phase carbon monoxide near the O1s-->2pi region. Both experiment and theory display a crucial difference between the x-ray absorption profiles obtained in the conventional and resonant scattering modes. Lifetime vibrational interference is the main source of the difference. It is demonstrated that such interference, which arises from a coherent excitation to overlapping intermediate levels, ruins the idea for obtaining x-ray absorption spectra in a lifetime broadening free regime.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Monoxide / chemistry
  • Scattering, Radiation
  • Spectrometry, X-Ray Emission / methods*
  • X-Rays

Substances

  • Carbon Monoxide