Gold(I)-catalyzed intramolecular hydroamination of unactivated C==C bonds with alkyl ammonium salts

Chem Commun (Camb). 2008 Jun 28:(24):2741-3. doi: 10.1039/b804081h. Epub 2008 May 19.

Abstract

A mixture of (5)AuCl [ = PCy2[2-(2,6-C6H3(OMe)2)C6H4]] and AgOTf catalyzes the intramolecular hydroamination of unactivated C==C bonds with primary and secondary ammonium salts.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Alkenes / chemistry*
  • Amines / chemistry*
  • Carbon / chemistry*
  • Catalysis
  • Gold / chemistry*
  • Ligands
  • Models, Chemical
  • Organometallic Compounds / chemistry*
  • Quaternary Ammonium Compounds / chemistry*
  • Solvents / chemistry

Substances

  • Alkenes
  • Amines
  • Ligands
  • Organometallic Compounds
  • Quaternary Ammonium Compounds
  • Solvents
  • Carbon
  • Gold