Abstract
The synthesis of a series of bicyclo[4.2.2]octenones and bicyclo[3.2.2]heptenones by 1,3- or 1,2-migration reaction from 2-vinylbicyclo[2.2.2]octenols is reported. These ring-expansion reactions were accomplished under basic or neutral conditions. Whether 1,3- or 1,2-migration takes place depends on endo- or exocyclic olefin displacement in the substrates.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry
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Anions / chemistry
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Bridged Bicyclo Compounds / chemical synthesis*
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Bridged Bicyclo Compounds / chemistry
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Carbon / chemistry*
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Furans / chemistry*
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Models, Molecular
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Molecular Structure
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Octanes / chemistry*
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Vinyl Compounds / chemical synthesis*
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Vinyl Compounds / chemistry
Substances
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Alkenes
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Anions
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Bridged Bicyclo Compounds
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Furans
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Octanes
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Vinyl Compounds
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Carbon
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octane