Combinatorial materials research applied to the development of new surface coatings X: a high-throughput electrochemical impedance spectroscopy method for screening organic coatings for corrosion inhibition

J Comb Chem. 2008 Sep-Oct;10(5):704-13. doi: 10.1021/cc8000458. Epub 2008 Jun 27.

Abstract

The objective of the study was to develop a high-throughput electrochemical impedance spectroscopy (HT-EIS) method for rapid and quantitative evaluation of corrosion protective coatings. A 12-element, spatially addressable electrochemical platform was designed, fabricated, and validated. This platform was interfaced to a commercial EIS instrument through an automated electronic switching unit. The HT-EIS system enables four parallel EIS measurements to be run simultaneously, which significantly reduces characterization time compared to that of serial EIS measurements using a multiplexer. The performance of the HT-EIS system was validated using a series of model systems, including a Randles equivalent circuit, an electrochemical reaction (Ti/K4FeCN6, K3FeCN6), a highly uniform polymer film, and several polymer coatings. The results of the validation studies showed that the HT-EIS system enables a major reduction in characterization time and provides high quality data comparable to data obtained with conventional, single-cell EIS measurement systems.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Biomedical Engineering / methods*
  • Coated Materials, Biocompatible* / analysis
  • Coated Materials, Biocompatible* / chemistry
  • Corrosion
  • Electric Impedance
  • Electrochemistry
  • Ferricyanides / chemistry
  • Materials Testing*
  • Potassium Cyanide / chemistry
  • Reproducibility of Results
  • Spectrum Analysis / instrumentation
  • Spectrum Analysis / methods*
  • Surface Properties
  • Titanium / chemistry

Substances

  • Coated Materials, Biocompatible
  • Ferricyanides
  • Titanium
  • Potassium Cyanide