Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture

Shumei Chen; Jian Zhang; Xianhui Bu

doi:10.1021/ic8007798

Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture

Inorg Chem. 2008 Jul 7;47(13):5567-9. doi: 10.1021/ic8007798. Epub 2008 Jun 7.

Authors

Shumei Chen¹, Jian Zhang, Xianhui Bu

Affiliation

¹ Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, California 90840, USA.

Abstract

A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.

Publication types

Research Support, N.I.H., Extramural

MeSH terms

Acetates
Camphor / analogs & derivatives
Camphor / chemistry*
Cations
Cobalt / chemistry*
Ionic Liquids
Macromolecular Substances / chemical synthesis*
Macromolecular Substances / chemistry
Molecular Structure
Stereoisomerism

Substances

Acetates
Cations
Ionic Liquids
Macromolecular Substances
Cobalt
Camphor

Abstract

Publication types

MeSH terms

Substances

Grants and funding