A "jellyfish" shaped green emitting gallium(III)-containing metallomesogen

Chem Commun (Camb). 2008 May 21:(19):2254-6. doi: 10.1039/b800030a. Epub 2008 Mar 13.

Abstract

The synthesis of the first gallium(III)-based liquid crystal has been achieved grafting around the metal centre two chelating 2-methylquinolin-8-olate anions and one monodentate 3,4,5-tris(hexadecyloxy)benzoyloxy ligand, allowing the resulting complex to be a soft luminescent material with the typical high quantum yield of pentacordinated gallium species.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzene Derivatives / chemistry
  • Crystallography, X-Ray
  • Gallium / chemistry*
  • Ligands
  • Liquid Crystals / chemistry
  • Luminescence
  • Organometallic Compounds / chemistry*
  • Quinaldines / chemistry

Substances

  • Benzene Derivatives
  • Ligands
  • Organometallic Compounds
  • Quinaldines
  • Gallium
  • 2-methylquinoline