Blue organic light-emitting supramolecular microfibers: the self-assembly of a 1,2,4-triazolo[1,5-a]pyrimidine derivative

Molecules. 2008 Apr 12;13(4):855-63. doi: 10.3390/molecules13040855.

Abstract

The design and synthesis of 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-2-thioaceto-(2-fluorobenzyl) hydrazone (TPTH), which self-assembled into supramolecular microfibers with blue organic light-emitting properties, is reported. This is the first occurrence of the molecular self-assembly of 1,2,4-triazolo[1,5-a]pyrimidine derivatives.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrogen Bonding / radiation effects
  • Light*
  • Microscopy, Electron, Scanning
  • Models, Molecular
  • Pyrimidines / chemical synthesis
  • Pyrimidines / chemistry*
  • Spectrophotometry, Ultraviolet
  • Triazoles / chemical synthesis
  • Triazoles / chemistry*

Substances

  • 1,2,4-triazole(1,5a)pyrimidine
  • Pyrimidines
  • Triazoles