Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand

Masato Ohashi; Marcin Konkol; Iker Del Rosal; Romuald Poteau; Laurent Maron; Jun Okuda

doi:10.1021/ja801771u

Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand

J Am Chem Soc. 2008 Jun 4;130(22):6920-1. doi: 10.1021/ja801771u. Epub 2008 May 8.

Authors

Masato Ohashi¹, Marcin Konkol, Iker Del Rosal, Romuald Poteau, Laurent Maron, Jun Okuda

Affiliation

¹ Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany.

PMID: 18461944
DOI: 10.1021/ja801771u

Abstract

A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently.